Strontium

View Categories

Strontium

4 min read

Orbitals and Energies #

Note – these are listed in BINDING ENERGY

 

Sr 3s ≈ 358 eV

Sr 3p ≈ 269 eV

Sr 3d ≈ 133 eV

Sr 4s ≈ 38 eV

Sr 4p ≈ 20eV

XPS of STO with Sr peak markers

Doublet Separations #

Sr 3d = 1.75 eV

Sr 3p = 10.4 eV

XPS of Sr 3d with doublet separation

Common Overlaps for Sr 3d #

P 2p – Zn 3s – Pb 4f – Eu 4d – Po 5p – Tl 5s – Sn 4s

Auger Energies #

Note – these are listed in KINETIC ENERGY

 

Sr MNN ≈ 100 eV

Common Binding Energies – Sr 3d #

Species #

B.E. / eV #

Charge Ref #

Reference #

Sr Metal

132

C 1s (285 eV)

SrCO3

132.6

C 1s (285 eV) – Carbonate = 289.5

SrO

131.2

C 1s (285 eV)

Theory and Background #

Strontium oxide, as is typical for group II oxides, is very basic, and will absorb CO2 readily to form surface carbonates.

Experimental Advice #

If analysing strontium oxides, GCIS etching may be required to remove surface carbonates. Sr carbonate does not decompose until ~ 875 degrees Celsius, so heat treatment in vacuo is unlikely to be an option.

Data Analysis Guidance #

Strontium has no particularly unusual features that complicate fitting.

Fitting parameters for copper metal

Reference Datasets #

 

Coming soon

References #

  1. Young, V., and T. Otagawa. “XPS studies on strontium compounds.” Applications of surface science 20.3 (1985): 228-248.. Read it online here.