Cesium

Doublet Separations

  • Cs 3d: 14 eV 
  • Cs 3p: 68 eV
  • Cs 4d: 2.3 eV
  • Cs 4p: 11.1 eV
  • Cs 5p: 1.9 eV

The Energies Listed are Binding Energies!

 

  • Cs 3s: 1217 eV
  • Cs 3p: 998 eV
  • Cs 3d: 726 eV
  • Cs 4d: 231 eV
  • Cs 4p: 162 eV
  • Cs 4d: 77 eV
  • Cs 5d: 23 eV
  • Cs 5p: 12 eV

The Energies Listed are Binding Energies!

Cs is primarily analysed via the 3d orbital

  • Fe 2p: 723 eV
  • Pt 4s: 724 eV
  • U 4d: 739 eV
  • At 4p: 740 eV

Energies listed are Kinetic Energies!

 

Cs MNN: ~ 563 eV

The Energies Listed are Binding Energies!

Species Binding energy / eV Charge Ref Ref
Cs2O 723.5 C 1s (284.8 eV) 1
CsF 724.2 C 1s (285 eV) 2
CsCl 723.9 C 1s (285 eV) 2
CsBr 724.2 C 1s (285 eV) 2
CsI 724.1 C 1s (285 eV) 2
CsClO4 724.4 C 1s (285 eV) 2
Cs2PO4 724.1 C 1s (285 eV) 2
Cs4P2O7 724.0 C 1s (285 eV) 2
Common Cesium Binding Energies

Cesium, a highly reactive alkali metal, has several important applications due to its unique properties. It is widely used in atomic clocks, which are essential for maintaining precise time standards. Cesium is also utilized in photoelectric cells, vacuum tubes, and as a catalyst promoter in various chemical reactions. Additionally, cesium compounds are employed in the production of optical glasses and in medical imaging.

Cesium can suffer preferential sputtering during XPS ion etching studies owing to it’s high volatility.

Cesium exhibits typically symmetric peaks.

Not available

  1. Band, A., et al. “Characterization of oxides of cesium.” The Journal of Physical Chemistry B 108.33 (2004): 12360-12367. Read it online here.
  2. Morgan, Wayne E., John R. Van Wazer, and Wojciech J. Stec. “Inner-orbital photoelectron spectroscopy of the alkali metal halides, perchlorates, phosphates, and pyrophosphates.” Journal of the American Chemical Society 95.3 (1973): 751-755. Read it online here.